The geography really doesn't matter, well it does but the west has mountains, desserts, plains, and so much more.
In reality, every single western LD train can do 90, but the freight railroads must upgrade the tracks to class 5 standards to allow for those speeds, and they really have no need for it which is why most don't go past 79, which is the limit for class 4 track. However BNSF has upgraded a sizable portion of their track to class 5 standards allowing the Chief to get to 90. Recently some track between St Louis and Chicago on the Texas Eagle route has also been upgraded to class 5, allowing for the TE and Lincoln Service trains to reach 90.